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@Chris.
Pro Team. Merino is good for colder weather, or if you're not sweating much. Synthetics will smell after use, but perform better at wicking sweat and keeping you dry. Merino doesn't smell so is useful for commuting etc, if you want to wear the same base layer each day. I use both for different things. Check out Craft mesh base layers on Wiggle and other brands for merino too. Not Planet X / On One; their merino sucks.