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Maybe worth a look:
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Yep, the powder is electrostatically charged and the thing your coating earthed, so the powder sticks to the metal due to static, if your subject you are powdercoating will not conduct then the powder will not stick. then you bake it at 200deg for 20 mins to melt/bake/bond the powder to the metal
Personally I'd go with signwriters paint (google hotrod pinstriping supplies for a supplier)
for lug lining over powder coat, it should stick well enough and as said above its not a high wear area, if you cock it up then use nitromorse to remove the paint and start again, it wornt touch the powder coat.