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@hugo7
I haven't ever used it, but my understanding (back when all things chrome took off) from mates who were into moding cars was that it is hard to do well. You'll need a black base layer to help give the shine it's reflection, and above all it needs to be done on a very even surface.
I think doing it effectively on a bike would be tough. Have a search on the internet, especially on car modification forums.
EDIT: here's some tips http://www.ehow.com/way_5374477_chrome-paint-tips.html