• Does anyone know of any decent alternatives to merino wool? Most wool irritates my skin a bit, and sadly merino wool does as well.

    This will make me sound like a twat but have you tried good quality merino? Devold are good (as previously mentioned by SF). Repeated washing in ecover (or suchlike) will soften them up and remove protective dressings which may irritate. Other than that it'll be cashmere, which I've heard Rapha are working on (probably).

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