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Only potential issue with this is it's quite acidic. If it's just your own used grounds I doubt the quantity would matter but if you're getting it by the butt load from a commercial operation you might end up changing the ph of your soil considerably. So, perfect for azaleas, camelias etc if you have them, but terrible for brassicas etc
If you can get used ground coffee from local coffee shop can make a very good mulch. Usually they have loads and happy to give it for free. No weeds germinate in it and it will feed the soil over winter.