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I wouldn't cut paint away on one fork-end and not the other. I think the approach would be to cut from the narrow surface of the dropout on both sides, so the wheel can seat fully into both slots and then re-seat the wheel. If it still sits wonky then look at filing the powder coat flat on the inside faces of the dropouts and after that maybe look at cold-setting it. I don't know if there's an equivalent of the string trick for forks.
Thanks All,
@Nef cheers for reposting the jpgs much appreciated.
@bluehuw am now running a QR front wheel so struggling to straighten and tighten like you could with a traditional axle.
@fabfurrymarmots will give the RJ film a watch, fairly hesitant to file away anything based on my skillset however can't see the harm in sanding the paint on the one side a bit more.
Have some time to take a proper look this weekend, if not maybe a trip to Varonha to have it looked at properly.