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I think it might be Polyamide that I don't get on with now that I think about it. I'm rocking a pair of the decathlon socks I picked up today, mostly cotton and much less sweaty and stinky after about 20 miles of otherwise sweaty riding. I'd never wear a cotton shirt to ride in so fuck knows why my feet are any different.
My go to are Planet X's 4 for £10 socks.