Immersion element in the hot water cylinder, job done.
That would be the hot water cylinder that contains your domestic hot water? The stuff that you run into your bath? So presumably not the water/inhibitor mix that's running through your radiators?
I feel like I'm missing something here.
You mentioned “and/or heat our DHW”… Yes, immersion element in the hot water cylinder.
If you really want to electrify, just make an ASHP work however you can. Anything else would be a big compromise.
@ffm started
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Immersion element in the hot water cylinder, job done.