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Generally your chain wears first, if you change it before it's too worn the cassette will be fine for a few chains, if not then you'll need to do both together, if you leave it way too long you'll wear the chainrings too but the wear usually spread over more teeth than the cassette so it can take longer/more chains.
I don’t think it is, personally. I have Dura Ace on one bike, but I fit 105 (or entry level SRAM) cassettes.
Are the chain rings worn or are you simply getting rid of the notorious Ultegra ones?