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But you can't dissociate ferric oxide with UV until you get to a power level where the shirt would be vapourised before the stain was touched 🙂
UV is good (or bad, if you don't want things to fade) for breaking up colourful organics into colourless fragments, but useless against most inorganic salts
You would be suprised how well sunlight will bleach stains out of white cloth too