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What adjusted net income is
Adjusted net income is total taxable income before any Personal Allowances and less certain tax reliefs, for example:trading losses
donations made to charities through Gift Aid - take off the ‘grossed-up’ amount
pension contributions paid gross (before tax relief)
pension contributions where your pension provider has already given you tax relief at the basic rate - take off the ‘grossed-up’ amount
When your tax
If it's salary sacrifice pension, which many are, then throwing more into your pension will reduce the taxable income. I expect there will be many doing this to scrape under the 100k threshold.