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Obvious but make sure that you've got everything lined up that you may need. Solicitor, mortgage, copies of (or easy access to) documents that you may need (e.g. payslips, bank statements, passport, a recent utility bill), access to a printer (you might not need it or you may desperately need to physically sign something, it seems to wildly vary), etc
Find out whether there's a chain and, if there is, how big it is, where it is, what the status of all the parties in it is, how much of a handle your estate agent has on it, etc
About to make my first ever offer on a property. Shitting it. Any tips for the next couple of weeks of madness?