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It's certainly a big commitment but sounds like a good plan!
The one thing I'd say is if you're going to get an ASHP anyway you'd be better off to let the ASHP do the DHW and direct the Solar PV to running the ASHP instead of an immersion. Every 1kw of energy you put into the immersion will give you approximately 1kw of DHW heating but if you put 1kw into the ASHP you'll be getting c.3-3.5kw of DHW heating...
Dream setup for our place - maybe in 10 years time (fitted new boiler in 2020 as couldn't face major renovation required to get the place efficient enough for ASHP)
Gonna be wallet crushing