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Yes:
Most goods arriving in the UK are liable to any or all of the
following taxes:Customs Duty
Excise Duty
Import or supply VATWorking out what customs and/or excise duty might be payable is basically impossible for ordinary people. Eg for the coat example what and how was it made? Perhaps start at https://www.trade-tariff.service.gov.uk/sections/11
I think a women's coat made of man made fibres and weighing more than 1kg will have VAT at 20% and import duty at 12% if coming from the US.
Is that not 20% VAT + whatever the import tax rate is on the product group and that's calculated from the value + shipping and the extra handling fee.