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Depends exactly what you mean by decent/high end (and general vicinity of Ventoux!) I suppose, but Hubert at Luberon Biking (in Velleron) has more than his website suggests. Maybe worth emailing or ringing (speaks a bit of English) to find out.
https://www.luberon-biking.fr/Or https://www.provence-bike.com/en/ in Avignon have a load, but only used them for tandems/ebikes before.
I don't think these guys go in for massively informative websites...
Can anyone recommend a bike hire place in the general vicinity of Ventoux for decent high end road bikes? All I’m finding at the moment are mtbs, e bikes and mamil chariots