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Assume you mean 250 vs 254. Nope, other than you will lose 2mm of cut capacity. The 24T from that set is the one I have, I think you will be happy with it / them.
FYI, Freud have updated their line and those blades are now superseeded by these:https://www.ffx.co.uk/product/Get/Freud-Fr23W001T-4059952521732-250Mm-X-30Mm-X-T24-T40-Table-Saw-Blades-2Pk
I don't know if they have gotten better or worse, the anti vibration slots look more contemporary...
Yeah - I think it's sort of a combination blade.
This looks like a decent set to pick up. It's fine on kerf thickness (min 2.4mm according to specs) but it's 4mm smaller on diameter (205mm vs 254mm) - can't see any reason why that would be an issue..?