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That sounds like a really good idea, not sure how the high reflectivity will look on the panel though. 80% reduction in solar heating sounds excellent though, if also used with something on the inside.
Acliff-
We have internal film on our windows (lower reflection value / lower mirror) and they work wonders. You'd definitely need external though as too much heat would be captured by the dark tint before being reflected by internal film.
With that level of reduction and the thermal barrier of the glass, I think it would completely solve the issue. Might as well give it a go...!
Soul
How about some of this?
Sticks to the outside rather than the inside so not affected by the tint.