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SBK is probably the most effective poison available to the public, pour it neat into the biggest holes you can drill in the stump, several inches deep.
@fizzy.bleach: if you allow about 6" of concrete in the area of pad nearest to the tree that should be fine.
ColinTheBald
I have a holly that needs to go (too near the house). I could use glyphosate but is there anything more interesting I can use?