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Mellow corn
Can't comment. Bourbon/Tennesee whiskey are min 51% corn in the mash, Rye is min 51% rye in the mash.
80% corn seems like a high sugar -> high alcohol method. Can't say I've ever had any Mellow Corn to the best of my knowledge.
'shine will have no maturation, so any maturation could only improve the flavour. I've never had moonshine but I've sampled raw spirit in Scotland and it's very unpleasant.
Aroogah
Mellow corn. Someone. Mainly @Aroogah I'm guessing.
It sounds intriguing. I've drunk shine. It's not going to be like that is it?