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The collect plus service used by Wiggle is the 24 hour one, they just don't advertise it as you need to place the order in time for it to be processed, which varies I guess by busyness.
The alternative is to order a 'hazardous' product, something like an aerosol product and it goes onto next day delivery automatically even if you select free delivery.
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I only use our 3-minute-walk Collect Plus location for (well you guessed it) Collect Plus, mainly Wiggle returns (no ASDA around for free returns and couldn't be arsed to go all the way to Roehampton) and the guy always asks "is there anything else" and I always reply "no" and feel unnecessarily guilty afterwards... I prefer paying that £9.99 yearly sub to get all packages delivered next day by Hermes/Yodel instead. I know they're supposed to be bigger nobs than Wiggle but they're usually OK in our neighborhood luckily/somehow.
Best thing to do with Wiggle orders is use the free Collect Plus service. It's almost always next day delivery and you don't have to put up with awful couriers. Granted I'm fortunate to live less than 1 minute away from a Collect Plus location.