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No.
Chloroquine: Formula: C18H26ClN3
Chloroquine phosphate: Formula: C18H32ClN3O8P2
Have an entirely different molecular structure and use.
I have no clue about what "medical grade" chloroquine would be taken, I'm assuming it wasn't formulated by a pharmacist into Plaquenil/Hydroxychloroquine however, so caveat emptor in terms of asking who is providing them with a potentially toxic substance in the first place.
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The Chloroquine in aquarium cleaner and the Chloroquine in anti malarial are one and the same. You are obviously correct about the addition of copper sulphate and other antimicrobials in aquarium cleaner though.
How about the people in Africa who overdosed on medical grade Chloroquine based on Trumps comments?