Assuming the frame is brazed using brass, your silver solder has a much lower melting point, so I wouldn't worry too much about damaging the fillets.
It wouldn't hurt to order a second disk mount or just a price of steel plate and practice soldering it to something other than a bicycle frame. Just to get an idea of the type of heat you need to focus into the mount rather than the thin tube.
Assuming the frame is brazed using brass, your silver solder has a much lower melting point, so I wouldn't worry too much about damaging the fillets.
It wouldn't hurt to order a second disk mount or just a price of steel plate and practice soldering it to something other than a bicycle frame. Just to get an idea of the type of heat you need to focus into the mount rather than the thin tube.