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The Prince in Stoke Newington has an upstairs room that's out of the way, toilets on the same floor, and they do Sunday lunch.
http://www.theprincen16.com/hire-space
(I haven't been there on a Sunday so don't know how busy it gets, but it's a nice space.)
The roast beef in the Adam and Eve in Homerton is one of the best pubs roasts I've ever had. It's fairly busy, but you could probably reserve an area that was pretty much contained. Worth it for the food...