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@Dramatic_Hammer - i agree, 96 is entirely sufficient. Not so sure about 16bit vs 24 bit though. Would like to run some tests sometime.
@mashton Qobuz's 24bit stream is roughly the same annual price as the 16bit service from Deezer. The ultimate hifi for me would be Roon + bluesound endpoints with a 24 bit streaming service going through a nice amp and pair of speakers. (I just got an email from Qobuz saying that Roon will be supported "very soon"). There's already a Roon server app for Qnap.
Saying that, I'm very happy with the pov solution of Plex + chromecasts and no streaming service. Probably Deezer would offer you more value as they have a family plan for £15. Then your kids can listen to the wiggly worm song without messing up your automatic playlists ;)
Why not Deezer?