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I don't live in London anymore, so my perspective has shifted quite a lot. To be honest I have some amazing memories of riding in London, but it's not really the city where you can have a relaxed ride enjoying the skyline, the architecture and the life around you. Exceptions apply, of course. The Thames path, as mentioned by @skydancer, was a favourite (Hampton Court to Richmond usually in my case).
ha, just enjoy london and forget about riding around?
staying for a bit so open for options....