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I went and spoke with a pharmacist before LEL about Volterol Vs ibuprofen which is what I would normally use for pain on long rides.
They told me if I hadn't had any adverse effects previously, then as long as I wasn't boshing them for weeks on end it would be fine.
It's also worth noting, Volterol is no longer available over the counter and is prescription only.
There's a few studies that show they do bad things to your guts and in my case in the TABR when I was trying to deal with the weird shin tendonitis thing they give you crazy cankles. My physio also warned me off them but for what specific reasons I can't recall.
I would consider using Voltaren but I stopped taking Ibuprofen after TABR, as in, didn't even carry them with me on TCR.