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Not sure, TBH. I've never build a 24h rear wheel with a shallow rim - the shallowest rim I've used myself on a 24h rear wheel with CX-Rays is a Kinlin XR31T which is pretty stiff. I suspect you'd be fine with CX-Rays, but I'd defer to more experienced wheel builders.
I built @Cycliste a rear wheel using an XR200 rim, which is light and quite floppy, and used CX-Rays on that but I used 28 spokes on the rear despite @Cycliste's feathery lightweightness. That was fine until a 6'1" chap called Alan rode over it after @Cycliste had gone over the handlebars. Wasn't so happy after that.
No. The stiffness of the spoke will depend on the Young's modulus of the material used and the cross-sectional area of the spoke. All steels have essentially the same Young's modulus (particularly as all steel spokes I'm aware of are made from 18/8 stainless steel or similar) so the only thing that will change in terms of spoke stiffness is the cross-sectional area. CX-Rays are just flattened Lasers, so will have the same area in cross section. If you want stiffer spokes then you're going to need either a different material (impractical) or a chunkier spoke (like a CX Sprint rather than CX-Rays).
Oh, and I'd recommend not lacing the front wheel radially if you're using Mack hubs. 2 cross front and rear.