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I can't really answer that. Have a look for studies that show what nutrients are lost during such events? Bare in mind the human body is pretty good at homeostasis - if you're lacking something you will likely crave something that will help fix it.
I didn't take any vitamins with me on TCR.
Bare in mind your "mcDonald's, pizza" diet is used by many people who aren't racing across Europe and they all live until they're at least 50... or can't get off the sofa to feed...
Based on a large meta-analysis someone did I think you're more likely to die sooner if you're taking multivitamins, but for a one-off thing like an ultra race rather than prolonged use, I'm not sure there's been studies that show benefit or harm.