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@ewanmac
I use Injinji Lightweight + Cool Max Wrightsock for blister prevention on long runs. I found the recommendation on fellrnr a few years ago when I was trying a few ultras and it was revolutionary. The only time i can remember getting even a hotspot with this combination was at mile 90 of the Thames path after 22hours of wet feet.
http://fellrnr.com/wiki/Blister_Prevention_and_Socks
Of course it's all personal... My gf has weird toes so doesn't like the ininjis and we're yet to find socks that stop blisters over about 15k.