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Might not be actual pepper spray, there's more friendly stuff:
https://www.police-supplies.co.uk/dog-deterrent
http://www.bite-back.net/about.phphttp://www.outdoorsmagic.com/forum/gear/dog-repellent-recommendation-please/48346.html
Careful with the pepper spray. It's classified as s5 firearm in the UK and subject to a 5 years custodial sentence. http://www.legislation.gov.uk/ukpga/1968/27