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Not really.
I pretty much leave the defaults.
I've whitelisted a few sites, including LFGSS... but these are ones that I truly know every single request for and have total confidence that there aren't trackers (beyond Google Analytics which is blocked by most people anyway).
To whitelist something you click the icon and press the big power button and then reload the page. Simple as.
Looking down my whitelist it's basically domains I own, sites I run, and a few Google ones (which I run in a different session, tracking cookies sandboxed from the rest of my browsing).
I've swapped over to origin. Is there any boxes/setting you'd recommend changing? Also, are google-analytics bad or do they just tell you things?