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That's a solvent based one. I try to avoid solvent based stuff these days as years of exposure has left me with a bit less tolerance for it. I'm not sure how much difference in grab there is but it's easier to clean up the excess non solvent one. Do be very careful that you don't get it on the face of the skirting or up the walls, have some solvent cleaning wipes around to keep things clean. It's a bitch to remove from emulsion once it's dried.
You'll probably have to fill the gap between the wall and skirting (at the top of the skirting) with mastic, resist the urge to do it with the glue!
Cheers, I've bought 3 tubed of this stuff seems pretty well rated for the job. That's a good tip about letting the wood acclimatise though.