Do the missions for The Brotherhood where you have to go and collect things. It will send you to places that are just filled with raiders so easy to kill and show you good areas to explore.
This in spades, especially after they gave you a power armour.
My advice would be to join all the faction and do all the mission bar the one that force you to choose a side.
Battle of Bunker Hill was confusing first time round, but managed to stay in BoS, Railroad and Institute's grace.
@edscoble started
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Do the missions for The Brotherhood where you have to go and collect things. It will send you to places that are just filled with raiders so easy to kill and show you good areas to explore.