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Any reason to why you want to keep it outside of your ISA? I use Hargreaves Lansdown for my S&S ISA and SIPP, I don't have but they also provide a Fund & Share account. Its worth shopping around for a provider though, HL aren't the cheapest but I find there website and apps the easiest to use and call centre is Bristol based.
Quick google search will bring up lots of comparisons/review but here are some of the providers available:
http://www.hl.co.uk
http://www.cavendishonline.co.uk
http://www.halifax.co.uk/sharedealing/
http://www.ajbell.co.uk
Does anyone on here do direct investment in stocks and shares through something like a share building account? I want to buy something to keep long term outside my ISA and wondered if anyone had experience and could recommend either a particular company/website?