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Will higher teeth on freewheel (eg 22t) reduce rolling resistance as much as the lower tooth chainring?
I don't think this is a relevant argument (for you and this bike), especially since budgeting is a (big) theme of this project (and not speed/efficiency). So I'd go for the cheaper solution.
I think you're correct in that less teeth cause less resistance, but firstly you won't be able to notice this and and secondly less teeth wear down the cogs/chainring faster.
If you're talking about the gear ratio then yes indeed, it doesn't matter if you use a smaller chainring or a bigger cog/freewheel; the ratio between the two changes in a way that the pedaling will become easier using both methods.
Will higher teeth on freewheel (eg 22t) reduce rolling resistance as much as the lower tooth chainring?
Paint won't last long as you say but I don't mind